New technology could allow batteries to last as long as 50 years

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By Press Trust of India | Updated: 25 April 2014 19:05 IST
Researchers have developed a new battery technology that could help create batteries that last longer than previously thought possible.

A team of researchers at the US Department of Energy's Oak Ridge National Laboratory (ORNL) have challenged a long-held assumption that a battery's three main components - the positive cathode, negative anode and ion-conducting electrolyte - can play only one role each in the device.

The electrolyte in the team's new battery design has dual functions: it serves not only as an ion conductor but also as a cathode supplement.

This cooperative chemistry, enabled by the use of an ORNL-developed solid electrolyte, delivers an extra boost to the battery's capacity and extends the lifespan of the device.

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"This bi-functional electrolyte revolutionises the concept of conventional batteries and opens a new avenue for the design of batteries with unprecedented energy density," said ORNL's Chengdu Liang.

The team demonstrated the new concept in a lithium carbon fluoride battery, considered one of the best single-use batteries because of its high energy density, stability and long shelf life.

When ORNL researchers incorporated a solid lithium thiophosphate electrolyte, the battery generated a 26 percent higher capacity than what would be its theoretical maximum if each component acted independently.

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The increase, said Liang, is caused by the cooperative interactions between the electrolyte and cathode.

"As the battery discharges, it generates a lithium fluoride salt that further catalyses the electrochemical activity of the electrolyte," Liang said.

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"This relationship converts the electrolyte - conventionally an inactive component in capacity - to an active one," he said.

The improvement in capacity could translate into years or even decades of extra life, depending on how the battery is engineered and used.

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Longer-lived disposable batteries are in demand for applications such as such as artificial cardiac pacemakers, radiofrequency identification devices, remote keyless system, and sensors, where replacing or recharging a battery is not possible or desirable.

"If you have a pacemaker, you don't want to undergo surgery every 10 years to replace the battery," Liang said.

"What if a battery could last 30 to 50 years? Our fundamental research is opening up that possibility through a new design mechanism," Liang added.

The study is published in the Journal of the American Chemical Society.
 

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